Exploiting electrochemistry to facilitate a radical alkene dichlorination.
How do synthetic chemists use fundamental, yet robust reactions to chemicals stitch together smaller fragments large and complex natural products? The Porco's Lab latest work might give you a taste of what it's like to exercise the art of total synthesis with a hint of inspiration from biology.
As versatile as enzymes already are, it's actually possible to engineer enzymes to catalyze reactions that are entirely new to nature!
Title: Electrochemical Capture and Release of Carbon Dioxide Authors: Joseph H. Rheinhardt, Poonam Singh, Pilarisetty Tarakeshwar, and Daniel A. Buttry* Publication Info: ACS Energy Lett., 2017, 2 (2), pp 454–461, DOI:10.1021/acsenergylett.6b00608 This article is a perspective from recognized experts in the field of CO2 capture and release. It specifically focuses on molecular CO2 binding-release agents whose... Continue Reading →
Click chemistry, a term used to describe a number of high yield reactions, is used far and wide by chemists. The azide alkyne Huisgen cycloaddition typifies click chemistry and awhile back, I described it as my favorite reaction.